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According to the IRS, these are not allowable deductions for you since the volunteer work was only done by your wife.
The test for the use of your car in order for you to deduct:
The amounts must be
- unreimbursed, and
- directly connected with the services you gave, and
- incurred only because of the services you gave, and
- not personal, living or family expenses.
Meals are also only deductible for the person who provides the actual service as a volunteer.
The expenses cannot be personal or family.
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