Brain Balance is considered an educational program outside of the school day. It costs $15,000 for 6 months. Is this therapy considered a deductible expense?

Form IRS's Publication 502:

You can include in medical expenses the cost (tuition, meals, and lodging) of attending a school that furnishes special education to help a child to overcome learning disabilities. A doctor must recommend that the child attend the school. Overcoming the learning disabilities must be a principal reason for attending the school, and any ordinary education received must be incidental to the special education provided. Special education includes:

• Teaching Braille to a visually impaired person,
• Teaching lip reading to a hearing-impaired person, or
• Giving remedial language training to correct a condition caused by a birth defect.

You cannot include in medical expenses the cost of sending a problem child to a school where the course of study and the disciplinary methods have a beneficial effect on the child's attitude if the availability of medical care in the school is not a principal reason for sending the student there.

Medical expenses are under the deductions and credits tab.

Is Brain Balance considered a qualified educational expense for a penalty free 529 withdrawal?

A 529 plan (aka qualified tuition plan or QTP) is operated by a state or educational institution with tax benefits and other incentives, making it easier to save for college, post-secondary training, and K–12 education expenses.

Formerly limited to higher education, 529 plan distributions can be used toward qualified K–12 expenses — up to $10,000 per student — in tax years 2018 through 2025.

If you took a 529 distribution of 10K or less to pay tuition, you don't need to report the 1099-Q in your federal return.  Save it for your records with tuition paid receipts.  Unfortunately, you won't qualify for an Education Credit for the balance you paid over 10K for K-12 expenses. 

If you took a distribution over 10K, you will need to enter your 1099-Q so TurboTax can calculate the taxable portion and penalty.

Click this link for more info on 529 Plans for K-12 Education.