No. You cannot "write off" your daughter's tuition. However, it is possible that you may qualify for an education credit. Depending on which year of education she is in and the type of program she is enrolled in, you may be able to claim the Lifetime Learning Credit or the American Opportunity Tax Credit.
You can take this for an unlimited number of years
Twenty percent of expenses up to $2,000
Non-Refundable meaning this can reduce the amount of taxes you owe, but if your tax liability is less than the LLC, your tax will be reduced to $0 and the rest of the credit is lost.
Cannot be claimed as a dependent on any one else's return
As a Married couple, your income must be below $160,000 for the full credit and below $180,000 for a partial credit
"Write off" her tuition? No. Paying her tuition is not an itemized deduction for Schedule A like mortgage interest or property tax, etc. If she is your dependent you can explore your eligibility for education credit like the American Opportunity Tax Credit.
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Yes. If she qualifies as your dependent, you may claim an education credit for the tuition and other qualified expenses paid, whether you paid them or she paid them (or grandma paid them).