Enter the alimony information in your Federal return. Then the amounts will be transferred to your California return.
There is a section in Federal > Wages and Income > Less Common Income > Alimony Received where you can enter any alimony that was paid to you.
Or, if you paid the alimony to someone else go to Federal > Deductions and Credits > Other Deductions and Credits > Alimony Paid section to enter the amounts you paid.
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